Synthesis and electrochemical behavior of the complex having μ2-nitrosyl moiety, as a two-electron reduction species of a {RuNO}6-type nitrosyl, [{Ru(μ2NO)}2(2,2-bipy)4]2+

Hirotaka Nagao, Noriharu Nagao, Dai Ooyama, Yoshinobu Sato, Tooru Oosawa, Hiroshi Kuroda, F. Scott Howell, Masao Mukaida

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Abstract

Synthesis of the title complex was accomplished. The structure involving a four-membered cyclic unit with negatively charged NO moieties could be established by 13C NMR measurements. Its electrochemical behavior was compared with that of [{RU(μ2-NO)}2(acac)4], which has the same cyclic unit, but with neutral charge on NO· moieties.

Original languageEnglish
Pages (from-to)473-474
Number of pages2
JournalChemistry Letters
Issue number6
DOIs
Publication statusPublished - 1 Jan 1998

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