Syntheses and structure of new dinuclear palladium(II) complexes with 1,1,2,2-tetraacetylethanate and β-diketonate

Yumiko Kobayashi, Noriharu Nagao, Seichi Okeya, Yutaka Fukuda

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Abstract

[Pd2(hfac)2(n-MeO)2] (1) (hfac-= 1,1,1,5,5,5-hexafluoro-2,4-pentanedionate) reacts with 1,1,2,2-tetraacetylethanediide (H2taet) to give a dinuclear mixed ligand complex [Pd2(taet)(hfac)2] (2) having bridging taet2- ligand. The terminal hfac-ligands in the dinuclear complex [Pd2(taet)(hfac)2] (2) are replaced easily by acac-to obtain [Pd2(taet)(acac)2] (3) (acac-= 2,4-pentanedionate). The structures of the two complexes obtained were determined by X-ray analysis.

Original languageEnglish
Pages (from-to)663-664
Number of pages2
JournalChemistry Letters
Issue number8
DOIs
Publication statusPublished - 1 Jan 1996

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