Di- and trinuclear [70]fullerene complexes: Syntheses and metal-metal electronic interactions

Yutaka Matsuo, Kazukuni Tahara, Takeshi Fujita, Eiichi Nakamura

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Buckyballs with studs: [70]Fullerene has been converted into di- and trinuclear complexes [M2 (C70Ar6)Cp 2], [M2(C70Ar7H)Cp2], and [M3(C70Ar7)Cp3] (M=Fe, Ru; Ar=aryl; Cp=C5H5; see picture, M purple, C pink, blue, gray) in which the metal atoms interact electronically through the [70]fullerene π-conjugated system. The structures and the electrochemical properties of these complexes suggest their use in molecular electronics.

Original languageEnglish
Pages (from-to)6239-6241
Number of pages3
JournalAngewandte Chemie - International Edition
Volume48
Issue number34
DOIs
Publication statusPublished - 10 Aug 2009

Keywords

  • Electronic interactions
  • Fullerenes
  • Metallocenes
  • Molecular electronics

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